Brad Pitt, Jennifer Aniston and Angelina Jolie
Back in 2005, Hollywood’s most powerful super couple, Brad Pitt and Jennifer Aniston, found their relationship crumbling as Jennifer announced that they were filing for divorce. Many believed that the split was caused by actress Angelina Jolie, who began filming Mr. and Mrs. Smith with Brad around the same time as his divorce. Though, the two denied reports that Brad cheated on Jen, just a year later, they confirmed they were an item when Angelina revealed she was pregnant with Brad’s child. Brad has since admitted that he fell in love with Angie on the set of their movie, but still denies that he cheated.